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Determination of foreign atoms in Hg1−xCdxTe by means of flameless AAS

Identifieur interne : 000336 ( Main/Exploration ); précédent : 000335; suivant : 000337

Determination of foreign atoms in Hg1−xCdxTe by means of flameless AAS

Auteurs : RBID : ISTEX:216_1992_Article_BF00633560.pdf

Abstract

The concentration of various foreign atoms in the compositional semiconductor Hg1−xCdxTe (x=0.2) has been determined by atomic absorption spectroscopy (AAS) and SIMS. The first problem of interest included the control of In doping of the (Hg,Cd)Te-melt solution and the epitaxial layers grown by step-cooling method. On the basis of analytical results it was possible to estimate the distribution coefficient k for the incorporation of indium into Hg1−xCdxTe. A value of k=3.2 has been found. This distribution coefficient did not change in the concentration range of In from 1×1016 atoms to 1×1018 atoms cm−3 in the melt solution. A distribution coefficient of about 3.0 was also determined by PIXE investigations. The second investigation concerned the level of background impurities in the bulk of HgCdTe crystals. The concentrations of some fast acceptors like Cu and Ag were determined. In the case of Ag it was confirmed, that the p-carrier concentration is influenced by the impurity level of Ag.

DOI: 10.1007/BF00633560

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<div type="abstract" xml:lang="eng">The concentration of various foreign atoms in the compositional semiconductor Hg1−xCdxTe (x=0.2) has been determined by atomic absorption spectroscopy (AAS) and SIMS. The first problem of interest included the control of In doping of the (Hg,Cd)Te-melt solution and the epitaxial layers grown by step-cooling method. On the basis of analytical results it was possible to estimate the distribution coefficient k for the incorporation of indium into Hg1−xCdxTe. A value of k=3.2 has been found. This distribution coefficient did not change in the concentration range of In from 1×1016 atoms to 1×1018 atoms cm−3 in the melt solution. A distribution coefficient of about 3.0 was also determined by PIXE investigations. The second investigation concerned the level of background impurities in the bulk of HgCdTe crystals. The concentrations of some fast acceptors like Cu and Ag were determined. In the case of Ag it was confirmed, that the p-carrier concentration is influenced by the impurity level of Ag.</div>
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